Cytosine monohydrate
WebMar 10, 2010 · The enantioselective formation of chiral crystal of achiral nucleobase cytosine was achieved mediated by the crystal direction selective dehydration of crystal water in the achiral crystal of cytosine monohydrate (P2(1)/c). Heat transfer from the enantiotopic face of the single crystal of cytosine m … WebCytosine monohydrate and the copper (II) complex of cytosine were characterized by recording IR, Raman and UV spectra. The various vibrational modes of the crystals have been classified using factor group and site group analysis. Vibrational assignments were proposed for both the systems based on the spectral investigations. Publication types
Cytosine monohydrate
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WebThe total free radical yield has been measured for crystals of five pyrimidine derivatives: thymine (T), 1-methylthymine (1MeT), 1-methyluracil (1MeU), 1-methylcytosine (1MeC) and cytosine monohydrate (C:HOH). Q-band EPR measurements were made on samples X-irradiated between 4 and 12 K. The G values … WebCytosine and cytosine monohydrate are representative biomolecules for investigating the effect of hydrogen bonds in deoxyribonucleic acid. To better understand intermolecular interactions, such as hydrogen bonds, between nucleobases it is necessary to identify the low-frequency vibrational modes associated with intermolecular interactions and …
WebNov 30, 2013 · Cytosine, a constituent of DNA and RNA, is a basic component of cytidine and deoxycytidine, and is essentially a flat achiral molecule. It is conceivable that cytosine was formed under prebiotic conditions.5 Cytosine forms achiral single crystals of the monohydrate ( P 2 1 / c) upon crystallization from water. WebJun 24, 2024 · Cytosine and cytosine monohydrate are representative biomolecules …
WebCytosine CpG methylation of the miR-34a promoter is a commonly observed … WebOct 1, 1973 · In the irradiated single crystal of cytosine monohydrate the radical with g 1 = 2.036, g 2 = 2.009, and g 3 = 2.001 and a doublet structure has been attributed to the thiocytosine species. Concentration of the thio-cytosine molecules depends upon the commercial source of the substance. The observed sulfur radical has a π-electronic …
WebThe crystal structure of both guanine hydrochloride monohydrate and guanine hydrochloride dihydrate is monoclinic, with four molecules in the unit cell (9, 10). For these two host crystals the orthogonal a*,b,c reference system has been used for the EPR measurements and analysis.
WebCytosine monohydrate Oxidation of cytosine produces a radical with sites of unpaired … can baby birds eat breadWebThe radicals were induced by X-irradiating single crystals of cytosine monohydrate, substitutionally doped with 2-thiocytosine. X-irradiation and measurements were carried out at about 15 K. The electron-loss radicals were found to be associated with the thiocytosine molecules in a proportion much above the thiocytosine/cytosine ratio in the ... fishing ban periodWebGeneral description. 2-Thiocytosine is a potential antileukemic and anticancer agent. … can baby be used for mineral oilfishing banner minecraftWebJan 1, 1983 · Neutron diffraction, thermogravimetric, and mass spectrographic measurements have been used to show that cytosine monohydrate loses its water of hydration at physiological temperatures (approximately equal … can baby bite nipple offWebApr 1, 1999 · Single crystals of cytosine monohydrate were x-irradiated at 10 K and examd. using K-band EPR, ENDOR, and FSE spectroscopy at temps. between 10 K and room temp. Three radicals dominated the low-temp. spectra. Radical RI is the cytosine anion protonated at the N3-position. A large coupling to HC6 and smaller couplings to … can baby bettas be togetherWebDec 31, 1995 · Recently, evidence has accumulated that cytosine is the initial electron trap in irradiated DNA. It has previously been observed that the protonation/deprotonation mechanisms and sites of the pristine purine/pyrimidine electron gain and loss centers depend upon the matrix. can baby betta fish live with parents